Abstract
The history of human-environment interaction is embedded in stone. Stones are
essential components of daily life and their various usage characterize certain
areas or chronological periods. The form of a stone object is the result of a
long chain of interactions with distinct bodies but the intangible life story of
any artefact is partially registered in its original material properties and
gradual physical alteration. Digital systems can be adopted for collecting these
invisible records and tracing a stone’s history. Chemical imaging and portable
spectroscopy are quick and non-destructive remote sensing techniques that can be
used to gather empirical data and track production and use of stone artefacts
over time. This article reviews the application of Near Infrared Spectroscopy as
a method for geochemical characterization of objects and as a tool for
provenance studies within the Mobima project, carried out by an
interdisciplinary team of archaeologists and chemists at University of Umeå,
Sweden.
Near Infrared Spectroscopy can be used for acquiring and processing spectral
information directly in the field, modelling datasets of big assemblages and
classifying objects.
Making stones’ biographies visible will help understanding the entanglement of
past societies and their geological landscapes.
Introduction
The life story of a stone artefact is an assemblage of events evident in the
tangible and intangible attributes of the object. By the term tangible, I
generally define that some of these attributes that are visible to naked eyes
like the color or the shape; other qualities, such as the cultural meaning that
the artefact assumed in a certain context, are invisible, and therefore
intangible; finally, some attributes related to the geochemical characterization
of the material are invisible but can be recorded through analytical methods.
Investigating the geochemical characteristics of stone artefacts is essential in
order to read the complex network of agents co-occurring in an object’s
biography [
Kopitoff 1984]. Digital tools can be beneficial in
order to decipher some of these evidences. Technology helps with reconstructing
narratives from otherwise invisible proofs; in particular, the application of
portable Near Infrared Spectrometry and Imaging represented a turning point in
the archaeological practice. This technology, particularly useful to gather
large geochemical datasets, has been successfully applied to the study of
various archaeological features at different scales, from landscapes survey to
characterization of lithic tools.
In this paper I discuss the epistemological implications with the study of stone
artefacts referring to new materialistic positions and the broader debate over
theoretical issues within archaeological sciences ([
Boivin 2005],
[
Jones 2004], [
Hodder 2012], [
Pétursdóttir 2012], [
Ruggles and Silverman 2009], [
Tilley 2004]). Related to that I describe different case studies
in which the use of technology supported the experimentation of new protocols
for acquisition and processing of empirical data. From in-field measurements of
soils and pigments, to hyperspectral imaging of ancient walls and pedagogical
implications in teaching archaeometry, I will consider potentialities and
concerns with the use of spectral remote sensing. All the case studies presented
are carried out within the Mobima project
[1]
(Mobile Imaging in Archaeology), the goal of which is testing and developing
applications of short-range remote sensing techniques on archaeological
materials with a specific focus on Near Infrared Spectroscopy (NIR).
Theories for disentangling an “ecology of
things”
[Bennet 2009]
The use of stone materials for various purposes is a constant throughout the
entire history of humanity. The mineral world has been quotidian to humans since
prehistory as a long-term entanglement: from hunter-gatherers’ knapped tools to
more recent mines, quarries, and buildings [
Foley and Lahr 2003]
[
Waelkens et al. 1992]. From early humans up to this day, stone materials
come in different forms, textures, sizes, and correspond to precise needs. The
selection of particular raw materials supply sources is mostly determined by an
empirical observation of rock's chemical and mechanical properties. For example,
a certain type of marble has been suitable for a particular sort of art and
architecture, obsidian appears to be an appropriate material for blades and
spear tips, while pozzolana sand is good for hydraulic mortars. Other contingent
factors equally occur in the choice such as the range of raw materials naturally
available, the network of trades/exchanges and the accessibility of the bedrock.
Considering these circumstances we can affirm that a stone artefact is always
the product of the joint agencies of human and stone mutually influencing one
another.
As Tilley states, “social relations are simultaneously
relations between material forms”
[
Tilley 2004, 217]; as a consequence of that, the study of socio-cultural dimensions of
stone artefacts should also be based on the analysis of their structure and
physical properties. Material and physical agents together with social practices
are co-occurring in the network of human-stone interaction [
Pétursdóttir 2012]. A stone artefact encloses the “objective nature of material culture and
the subjective experience of human beings”
[
Ruggles and Silverman 2009, 11], as the product of a long chain of interactions with other bodies
generating variations in their material tangible properties: rain, frost, and
sun provoke geochemical modifications on stones leading to decay and erosion; a
Roman marble inscription celebrating a victorious emperor can be cut and reused
as building material for a Romanesque cathedral. Various agencies are entangled
and can be categorized by using different chronological and spatial scales. For
example, usage of raw stone materials can be mapped by reconstructing the steps
of exploitation and colonization of natural resources in a region, while the
network of trades and transport is taken into account by tracing movements of
people and stone goods over longer distances.
The combination of a stone’s tangible and intangible properties is better
understood via its materiality, defined as: “a notion that encompasses the view that
material and physical components of the environmental and the social
practices enacted in that environment are mutually reinforcing”
[
Jones 2004, 330]. Every object is part of a texture of matters, as outlined by [
Hodder 2012], and the interactions between
humans-artefacts-environments can be read from the point of view of things. The
focus on an object’s materiality shifts the archaeological perspective on
cultural interpretation; the artefact is no longer a clue to be decoded but an
essential component of the past characterized by material properties that must
be explored in detail [
Boivin 2005]
[
Jones 2004]. To which extent can the study of stone artefacts’
materiality depend on the analysis of their physical properties? The
socio–cultural environment and the geological characteristics are equally
necessary to describe an artefact. In this sense, cultural interpretation and
archaeometric data are necessarily entangled.
Various terms have been used to refer to the study of geochemical characteristics
of stone artefacts. These terms often carry implicit theoretical connotations.
The debate over methods for collecting data concerning the geochemical
characteristics of objects is developed in the field named provenance studies
and generically defined by [
Malainey 2011] as the study of
attributes suitable for tracing the raw material the artefact was made of and
where it was manufactured. Although the words provenience or provenance are
equally adopted to define this particular branch of archaeology, the use of one
or the other term is ambiguous. A debate has been undertaken by scholars
suggesting that the terms provenance and provenience actually refer to different
concepts and not only a spelling variation
[2] ([
Boivin 2005], [
Joyce 2012], [
Jones 2004], [
Malainey 2011], [
Price and Burton 2011]). The distinction
between provenience and provenance is often related to the context. For example,
when associated with museum and archive policy for item acquisition, the word
provenance implies “the history, the
life of the object” including previous owners, while provenience is
the “find spot”
[
DeAngelis 2006, 398]. In relation to archaeological research, provenience is defined by Price
and Burton as either “the place of
discovery” of an object or its “place of origin”
[
Price and Burton 2011, 213]. I refer to provenance and provenience as indicating two different
methodological and theoretical strands.
In the US, the term provenience is used by archaeologists and chemists
principally indicating the place of origin of the raw material an artefact is
made from. A consequence of this concept is the provenience postulate that
states that: “the chemical differences within a single
source of material must be less than the differences between two or more
sources of that material, if they are to be distinguished”
[
Price and Burton 2011, 214]. In these terms, the study of an artefact’s provenience poses geochemical
analytical problems, especially for the definition of the material’s signature.
Consequently, the success in the application of the postulate is uncertain from
case to case and it depends on: type of materials, geographic distribution of
sources, analytical techniques, budget/costs, time, and type of artefacts [
Price and Burton 2011]
[
Malainey 2011]. Nevertheless, a strict focus on the analytical
issues related to the application of the provenience postulate risks resulting
in a never-ending debate on different methods’ technical details. The use of
analytical methods must be related to the transformation of the paleo
environmental record and the problematics of artefacts’ proveniences need to be
contextualized in the site development dynamics.
I apply the term provenience to indicate the field of studies that aims at
finding the origins, the sources of the raw materials, marking a direct thread
which ties together supply-artefact and relies mostly on geochemical analytical
techniques. Provenience is a markedly static concept, which does not include the
interaction of the object itself and the environment.
Nevertheless, the origin of raw materials is to be considered part of a more
comprehensive narrative of provenance: the chain of events that shaped what an
artefact looks like when we observe it. Objects are constituted primarily of raw
materials and are continuously altered, changing their properties and becoming
other things [
Joyce 2012, 124].The ecosystems, in which
artefacts and sources are situated, play an important role in defining a stone’s
geochemical signature as they are in continuous change. Quarries, mines or
outcrops are exposed to weathering and buried sites are influenced by post
depositional processes (modification occurring to the sediments once they are in
place), both of which are capable of causing a chemical alteration of the
geological materials. Environmental and human factors can make objects move.
Erosion, water transportation or human activity can carry artefacts far from
their place of production. All these movements and transformations might
interfere with a clear identification of the geochemical characteristics of
objects and sources, but are fundamental for defining the biography of the
artefacts.
Provenance is therefore more appropriate to refer to the life of the items in
context, it applies to the entangled history of humans and stone materials as
traced by the co-occurrence of physical characteristics and acquired meanings.
Digital tools can help make visible the proofs of ongoing narratives, expressed
in objects’ intangible properties.
Methods for assessing the invisible
Artefacts are not crystallized traces of human activities but active players in
dynamic environments, referring to the interaction of distinct objects on
different scales of matters [
Bennet 2009]. The concept is not new
in archaeology and it can be backtracked to Schiffer’s work (1987) on the
Formation processes of the archaeological record.
Although Schiffer makes a distinction between systemic contexts and
archaeological contexts, somehow a limitation to the hypothetic interactions
between humans and things, he classifies the processes that influence artefacts
in a physical way. Variations in the material attributes of objects should be
recorded and linked with the biography of the artefact itself, defined as
provenance. Measuring artefacts’ properties is a fundamental step for
understanding the stories of their provenances. This process of mapping
interactions is extremely challenging due to the high variability of physical
modification that may occur to things and that things contribute to. Considering
the material qualities of artefacts as the center of a network of social
relations, symbolization, physical interactions with the environment and
subsistence, we are able to formulate more interesting research questions within
a more comprehensive theoretical frame [
Dunn and Woolford 2012]
[
Dunn et al. 2012]. A solid narrative of provenance relies on the
association of epistemological issues, sampling strategies and tools for the
collection of empirical data. A theory of things based on objects’ physical
properties is linked to the discussion on methods for gathering and processing
information.
Digital techniques, analytical tools and sampling strategies applied in different
case studies then must be calibrated on the target, adapted to record the
complexity of the network between humans-things and environment. The physical
and material properties of a stone artefact are measurable attributes, and
observations that can be conducted refer to standard systems: the geological
description (petrographic-mineralogical), the chemical characterization
(elements and properties, carried out using various methods) and the
documentation of traces resulting from the contact with other bodies (tool
marks, for example). Consequently, analytical tools can be designed to fulfill
the demand of a certain type of empirical data [
Jones 2004]
[
Bray and Pollard 2005], avoiding the risk of generating datasets not
comprehensive of the set of issues that are the focus of theoretical practice
[
Boivin 2005].
A substantial problem for the determination of stone materials’ characteristics
with geochemical quantitative analysis is represented by the choice of sampling
strategies. Geochemical methods applied in provenance studies (petrographic
analysis, X ray fluorescence, mass spectrometry, instrumental neutron
activation, just to mention some of them) are often destructive, expensive and
time consuming. Analytical techniques carried out in laboratories require a
careful selection of the objects to be studied. The system applied is often a
convenient sampling method based on project specific needs and related research
questions [
Orton 2000]. I argue that this could result in a biased
dataset representing some specific targeted queries to the detriment of the
evaluation of the entire variability of the objects’ population. In selecting
variables to record and items to measure, archaeologists are influencing the
questions that can be posed to materials [
Boivin 2005], testing
tools for recording and visualizing the material properties of a more
comprehensive range of artefacts is essential in order to defy workflows based
only on destructive and punctual analysis.
The choice of using Near Infrared Spectroscopy relies on practical and analytical
strategies. NIR is a technique based on recording different molecular vibrations
in the Near Infrared band of the electromagnetic spectrum. It is a
non-destructive method that requires the use of controlled light source and
digital captors (like cameras or probes) and that can be implemented in various
contexts. NIR covers the spectrum region between 700 and 2500 nm and contains
absorption bands corresponding to overtones and combinations of fundamental C-H,
O-H, and N-H vibrations. NIR has a scarce sensitivity to minor constituents, as
a Near Infrared Spectrum doesn’t present clear peaks but often it shows more
broad bands that are the result of aligned peaks [
Bokobza 1998].
Considering NIR properties, the identification of elements from a single
spectrum is often not worthwhile and a fingerprint approach is preferable. One
big advantage with the use of NIR is the fact that it is a nondestructive method
requiring a very simple sample preparation, and performs a long series of
measurements in a short time. This makes it a method with interesting
possibilities of application in archaeological research, recording spectra from
various elements several times. NIR is largely used as a control test in
pharmaceutics industries, agriculture, food production and geology. For example,
NIR has been applied to a wide range of geologic problems: mineralogical mapping
of lunar surface [
McCord and Adams 1973], mineral exploration [
Goetz et al. 1983], mineralogical analysis of drill cores [
Kruse 1996], field mapping of expansive soils [
Chabrillat et al. 2002] and field mapping of mineral assemblages for gold
deposits explorations [
Bierwirth et al. 2002]. The development of close
range hyperspectral imaging associated to LIDAR scanning has allowed rock
characterization of quarry walls both with natural and artificial light.
Mineralogical variation in vertically oriented rock faces has been mapped at
high resolution using a light weight hyperspectral imager [
Kurz et al. 2012].
Moreover, several spectral reference libraries are already available as open
source from various agencies. The USGS has a database consisting of over 1300
spectra available
[3], the library
contains minerals, man-made materials, vegetation and other materials. Jet
Propulsion Laboratory ASTER Spectral library version 2.0
[4] contains more than 2400 spectra of
minerals, vegetation and man-made materials.
Mobima project’s target is to construct an experimental analytical protocol for
archaeological materials which could be applied to features directly in the
field or to large datasets of artefacts in laboratory. There are various
portable instruments on the market which allow us to multiply the number of
measurements and bring the laboratory directly to the field (for example,
portable X ray fluorescence or portable Raman spectrometers), due to the
constant development of tools for non-destructive analysis and handheld devices.
On the other hand, as a consequence of the use and misuse of these methods, an
opinion has spread that portable instruments are not sufficiently reliable for
chemical elemental characterization of archaeological objects ([
Frahm 2014], [
Shackley 2012], [
Speakman and Shackley 2013]). This opinion of portable instruments is likely
due to an insufficient evaluation of the data gathered and the instrument
settings/calibration, which had as an outcome the production of datasets
unacceptable in terms of accuracy for fulfilling the provenience postulate.
By using field-portable and quick image-based techniques, it is possible to get a
more global overview on materials’ surface chemical characteristics. NIR can be
used as a unique tool for categorizing different types of raw materials (using
spectral data as common fingerprints for same source artefacts) or as an
exploratory method to set sampling strategies for elemental analysis. The
adaptability of NIR instruments makes it possible to be applied to almost every
kind of material. The extended collection and interpretation of spectral data
could become a digital added value to an artefact’s optic description.
Within the Mobima project two different devices are used for testing Near
Infrared Spectroscopy on archaeological materials.
- The portable micro probe produced by JDSU (now Viavi) covers a wavelength
range of 908-1676 nm. The probe has two integrated tungsten lamps and a
captor that is 5x3mm wide. The probe is connected to a tablet used to manage
and store the records. The instrument is calibrated every 5 minutes (on
average) using a white and a black reference (see figure 1, on the left). The portable probe is suitable for
research directly in the field, is easy to carry and can record spectra in a
few seconds.
- The Sisuchema Pushbroom short wave infrared hyperspectral imaging system
(1000–2498nm) is a non-portable Near Infrared (NIR) imaging system used in
the laboratory mounted on a conveyor belt for taking pictures of large
artefact datasets or sample series (see figure
1, on the right).
A parallel experiment is carried out testing the use of a modified reflex camera
for field imaging. By removing the blocking filters and adding two different NIR
filters (720 and 950 nm), it is possible to transform a digital SLR camera into
a tool for NIR multivariate imaging. The spectral information obtained with this
instrument is not as detailed as that collected with the Hyperspectral imager,
but it can still be used as a quick data evaluation technique (details in [
Geladi and Linderholm 2015], [
Allios et al. 2016]).
These instruments in combination grant good coverage for collecting Near Infrared
spectra both in the field and in the laboratory. Both the NIR probe and the
Hyperspectral camera work connected to a tablet or a PC so that the data can be
evaluated directly during the field/lab operation.
NIR potentialities and limits for archaeological research can be evaluated
referring to the two instruments tested within the Mobima project (JDSU microNIR
and Sisuchema Pushbroom, mentioned above) according to precision, accuracy,
reliability and validity
[5].
Working with the Micro NIR in the field, there might be a precision problem with
the positioning of the probe on the surface of the materials. The captor window
inside the instrument is usually small compared to the holder (4x2 mm, placed in
the center of a 4 cm wide holder): for this reason addressing a measurement on a
very specific spot becomes problematic (considering also the non-homogeneity of
many rock types). The calibration in the field is performed using a white
reference (100% reflectance) made by spectralon, a fluopolymer with the highest
diffuse reflectance of any known material in the near infrared region of the
spectrum. For the black reference (0% reflectance), the producers’
recommendation for the JDSU probe is to calibrate by pointing the spectrometer
in a dark corner. In field conditions finding a spot with no natural or
artificial light disturbance might be difficult, therefore an easy solution has
been adopted placing the probe on a sheet of fine grained black sand paper.
Accuracy of NIR portable spectrometers and imaging systems can be evaluated
within an internal validation model and in comparison with other non-destructive
and portable techniques. The method that has shown to be suitable for the
correlation, accordingly to our project aims and goals, is portable X-Ray
Fluorescence spectroscopy (XRF)
[6].
XRF is a well-established technique used for sourcing materials in archaeology.
Scholars have been debating the applicability of portable XRF devices for
provenience studies ([
Frahm 2014], [
Shackley 2012],
[
Speakman and Shackley 2013]) and the discussion about the reliability and
the treatment of such data is still open. A major problem is presented by the
application of calibration systems. Handheld portable XRF devices are often sold
with a series of calibration models loaded in the system. The models are
calibrated through a fundamental parameter routine against samples of known
composition. This type of calibration is good for a presence/absence assessment
but not accurate enough for provenience elemental analysis [
Shackley 2012].
NIR in practice
Within Mobima, the research focus is on method development and experimental
design. For this reason, the project is run on various materials and sites.
Portable NIR spectroscopy has proved effective in relation to some case studies
already published and in particular for stone materials characterization ([
Allios et al. 2016], [
Linderholm et al. 2013], [
Linderholm et al. 2015]).
The first application of NIR in archaeology within this framework was the study
run on bone fragments classification in archeological soils by means of NIR. The
NIR hyperspectral imaging was applied to the identification of animal bone
material in complex sieved soil-sediment matrices from a mid-Mesolithic site in
northern Scandinavia. The whole dataset of bones and teeth samples was analyzed
through image based nondestructive techniques and used as reference for the
identification of fragmented skeletal material on soils from the excavation. The
information about the bones’ chemistry-mineralogy variability within the site
and in different layers provided information about the state of preservation of
the materials [
Linderholm et al. 2013].
A field based study of rock paintings in northern Scandinavia was carried out
during the autumn of 2014 using the NIR portable Micro probe. The detailed
results from the targeted analysis on a panel in Flatruet, Härjedalen, Sweden
show a large spread in spectral data from red paintings and the background.
Nevertheless, evidence of clustering was observed and using multivariate data
analysis and it was possible to separate the information related to the
paintings.
Using partial least squared discriminant analysis and setting bedrock and paint
as discriminant variables, the separation was clear and the model was used for a
classification test. The classification was run on 20 samples (10 paint and 10
background) and only three spectra were misclassified. An analytical problem
emerged due to the spread of secondary iron oxides from precipitation on the
surface of the rock wall but this resulted in measurement noise rather than a
real item classification problem. In a local model scale, looking at the
different composition of pigments within two painted figures, it was possible to
spot the difference between two different elks feasibly painted with different
red pigments [
Linderholm et al. 2015]. This study opened the way for
further on-site analysis of painted prehistoric panels, highlighting some
analytical problems and showing how they could be overcome.
Since February 2016 a comprehensive field study has been launched on the medieval
city walls of the city of Carcassonne (France). The study was initiated as an
international collaboration between the Umeå University (Sweden), the French
university of Rennes 2 and IRSTEA Montpellier. The goal was the application of
different spectral techniques for the study of the use of raw stone materials in
the fortress walls. The data were collected using a NEO HySpex-320m-e camera
(1000-2500 nm), mounted on a pulley system and moving on a rail. The
Hyperspectral data were associated to NIR enhanced color photography and point
measurements performed with NIR microprobe and compared to portable XRF (Thermo
Scientific Niton XL3t ED-XRF analyser using a 50 kV X-ray tube with an Ag target
and a Si (Pin)-detector and applying the Mining Cu-Zn calibration). The dataset
was processed through multivariate methods in order to evaluate the clusters and
draw a first overview of the materials’ provenance [
Allios et al. 2016].
The association of various methods allowed the understanding of the dynamics of
stone use and re-use on the entire extent of the walls in different
chronological periods. Such a wide perspective is crucial to understand the
impact of the monumental construction in the landscape in terms of materials
supply and exploitation of quarrying sites.
Near Infrared Spectroscopy has been successfully used also for educational
purposes, in particular within the archaeological field school for master
students in the environmental archaeology program at Umeå University. On
excavation, students collect and process data in real time. This approach is
pedagogic for understanding the correlation between features observed in the
field and chemical properties registered in the Infrared Spectra.
Non-destructive field-based analytical techniques are taught together with
traditional sampling strategies and wet chemical laboratory analysis.
Applications of Near Infrared Spectroscopy in geology are mostly related to
industrial and mining research, while within archaeological
provenance/provenience studies elemental analysis is generally preferred. There
is still some resistance amongst archaeological geochemistry specialists towards
the applications of NIR for stone materials studies, motivated by the
difficulties in making element identification from the spectral data. This
argument is legitimate when the research goal is sourcing materials fulfilling
the “provenience postulate” (mentioned above, [
Price and Burton 2011]) only according to defined and quantified geochemical
association of elements. It would be a mistake to focus on measurement precision
to the detriment of the archaeological accuracy needed for a determined case
study [
Shackley 2005]. Within the Mobima project, the Near
Infrared spectra are often not evaluated for peaks identification but their
shape corresponds to the combination of chemical elements constituting a single
material bar code. Of course, this approach involves some inconvenience. The
direct comparison of chemical elements in stone materials obtained with other
analytical methods becomes arduous. Nevertheless, by multiplying the
measurements and processing the dataset through layers of multivariate analysis,
it is possible to create local models for clustering and sourcing.
Data mining, data minding
NIR spectroscopy can be used extensively as a digital screening method. The
application of this type of target specific portable spectroscopy or imaging
technique provides a detailed overview of the physical-chemical characteristics
of the materials. NIR turns into a crucial tool for looking at the large scale
variability of stone artefacts’ qualities and an essential sampling tool for
elemental analysis. The application of NIR to archaeological research makes it
possible to collect big datasets in short time [
Allios et al. 2016]
[
Linderholm et al. 2015]. The first field test application of the NIR
probe for the study of rock paintings allowed the collection of 1432 spectra in
the near infrared within working five days and from six different sites [
Linderholm et al. 2015]. The time for each measurement is about 1-2
seconds and there is no limit to the number of records. The data collected with
the Micro probe are stored as data matrix files in which the
variables/wavelengths are reported. The spectra can be visualized on the
laptop/tablet in real time during the acquisition.
The hyperspectral image files are more laborious to process. Depending on the
size of the image the dimension of the data files can vary from about 50 to 500
MB (raw format). When working with the lithics from a site, for example, we have
to deal with image datasets of up to 22 GB for a total of 2261 objects analyzed.
For these reasons the computing time for processing information must be taken
into account. The use of a large dataset means that the sampling bias becomes
less influential, and the responsibility of the researchers in choosing the
fragment to analyze is reduced. The procedures adopted by the Mobima Project
members are based on a Big Data Approach, consisting in hierarchical and cluster
models. Archaeometry, like the rest of archaeology, is involved in the
big
data challenge
[
Gattiglia 2015], both from a computational and a theoretical
point of view, statistical and interpretative tools are improved to handle large
amounts of information. When analyzing a big dataset lacking in structure
(meaning not structured in a SQL database) with statistical tools we can spot
similarities and patterns among the data (see
figure
3). This modus operandi is usually referred to as data mining and it
allows to cross reference large datasets and create clusters of aggregated data
[
Boyd and Crawford 2012]. Within a data mining practice the information is
processed in order to find correlations rather than causations [
Gattiglia 2015].
In order to follow this path we apply methods issued from the data driven
discipline of chemometrics, which focuses on the application of mathematical
methods for analyzing chemical data. Chemometrics deals with both descriptive
and predictive analysis and it is grounded especially in multivariate data
analysis. Principal Component models are used as exploratory tools to spot
patterns in the data matrix. Image mapping is based on cluster analysis so that
similar spectral values can be projected directly on the picture. Spectral
information is evaluated and associated to the spatial distribution on the
object surface. The data collected are processed using the software Evince by
Prediktera, which is designed for operating image mapping, spectral
transformations and multivariate statistics (more details on the software at
www.prediktera.se).
NIR technology associated with chemometrics becomes a powerful tool for screening
and evaluating big datasets, by working on associations among different
materials in a way that couldn’t have been possible with other elemental
analyses. The visual approach to chemical data that can be reached with these
tools shifts the focus on the variability of the chemical properties of stones
in a local model instead of a determination of the singular elements. The
visualization of spectral data directly during the acquisition via digital tools
represents a substantial difference between NIR and other analytical methods.
The invisible attributes of stones can be disclosed while looking at the
artefacts themselves, providing an advantageous tool for sampling and work
planning.
Conclusions
In the first section of this paper the theoretical frame of the study of stone
artefacts was problematized in order to delineate a more solid protocol for
tracing the provenance of objects. Moving from a theoretical body for the study
of stone-human entanglement, focusing on non-human agencies, to the empirical
data collection represents a challenge for our discipline.
It was shown how the adoption of new analytical procedures could be helpful for
acquiring geochemical data, in particular a sampling strategy targeted to the
reduction of the influence of researchers’ prejudice about materials could help
focus more on artefacts’ materiality.
NIR offers a range of interesting possibilities. Portable spectrometers and
imaging systems are versatile instruments that can be used as short range remote
sensing tools both in the laboratory and in the field. The technical peculiarity
of this type of spectrometry makes it possible to distribute the measurements on
the surface of the objects allowing a diffuse quantification of the chemical
properties and the direct observation of their variability.
Visualizing and increasing exponentially the number of measurements performed is
a critical step in order to build an analytical protocol adequate to represent
the peculiarity of chemical-geological information at different scales. The
preliminary results from the Mobima project show how the application of NIR
technology represents a resource for looking at the intangible strands of an
artefact’s biography. Near Infrared Spectroscopy can be adopted as a screening
technique for picturing geological materials’ chemical topography, involving in
the analysis information that would have otherwise been neglected. In different
archaeological contexts NIR tools can provide precious information, however the
application is dependent on a good understanding of the spectral signatures of
various materials, together with statistical modelling.
NIR spectra datasets are useful sources of information about correlations between
objects; however, the archaeologists still hold responsibility for the
interpretation of these patterns. Knowing what type of pigment was used in a
rock painting gives us a suggestion about the painter’s technological know-how
and the materials she/he had at disposal, but it could indirectly contribute to
the definition of a typo technological series of paintings on different sites.
NIR spectra can help us understanding how much of the Roman walls of Carcassonne
still stand but will not suggest what happened to the rest of the blocks.
As other digital analytical tools, NIR can help record the visible and invisible
traces of events embedded in the physical form of a stone artefact; discerning
how these data are tied together and with other elements is the challenge thrown
down to researchers.
Biographies of stones are intertwined to help us estimate the mapping of bodies
and agencies on different scales; the combination of proofs collected with these
tools can be the foundation for interpreting the invisible. In a “past formed from a turmoil of multiple voices”
[
Bray and Pollard 2005, 181], the stone call can be detected by means of digital analytical tools.
Acknowledgements
Thanks to the Mobima project: Johan Linderholm, Paul Geladi for the work done
together in the last two years. Thanks to Johan Hallqvist, Dominique Allios and
Lorenza La Rosa for feedback.
The Marcus and Amalia Wallenberg foundation is to be acknowledged for financially
supporting this project.
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